glycol ether eb uses

It is an excellent solvent for household and industrial cleaners, rust removers, and disinfectant. Foam in fire extinguishers, oil spill dispersants, asphalt release products, degreasers, and varnish removers are a wide array of products that use glycol ether EB as a solvent. Such treatments should remove solvent residues that could be considered food additives. A centrifugal pump is suitable for transfer services. After the original test time, each retest should be one-half the original period. (3) Alsop, G. M., R. A. Conway, “Bacterial Growth Inhibition Test,” Journal Water Pollution Control Federation, Vol. The petroleum industry relies on glycol ether EB as a drilling stabilizer, oil slick dispersant, and in water-based and oil-based fracturing fluids. The use of glycol ethers also allowed exploitation of temperature‐change‐induced phase splitting behavior to concentrate the desired product. The toxicity commonly associated with the longer chain ethylene-series homologues involves red blood cell haemolysis with secondary effects relating to this haemosiderin accumulation in the spleen, liver and kidney, and a compensatory haematopoiesis displayed in bone marrow. As a result, it provides unique cleaning power for removal of both watersoluble and greasy (water-insoluble) soils. Table 2 (continued). The customer should furnish the information in this publication to its employees, contractors, and customers, or any other users of the product(s), and request that they do the same. (1) This EPA Regulation cross-references to FDA Regulation 182.99 and 582.99 (21 CFR). Acute (short-term) exposure to high levels of the glycol ethers in humans results in narcosis, pulmonary edema, and severe liver and kidney damage. † The physical property data listed are considered to be typical properties, not specifications. CARBITOL solvent is an important solvent in non-grain-raising wood stains and serves as a component of industrial cleaners. Glycol ethers are either "e-series" or "p-series" glycol ethers, depending on whether they are made from ethylene oxide or propylene oxide, respectively. Hexyl CARBITOL solvent, like Hexyl CELLOSOLVE solvent, displays a strong hydrocarbon-type solvency. It is an excellent solvent for many coatings resin types, including alkyd, phenolic, maleic, epoxy, and nitrocellulose resins. You’ve likely encountered these chemicals — from glycol ether EB to glycol ether DB — in countless industrial applications. Due to its slow evaporation and excellent solvency characteristics, Hexyl CARBITOL solvent contributes good flow and leveling to high solids coatings during the drying/curing cycle. monobutyl ether . The use of glycol ethers has changed significantly over the past 30 years. It may be used to coalesce waterborne latex coatings and to balance solvency and volatility in high solids coatings. The increased ether functionality of Hexyl CARBITOL solvent provides greater solubility with water than Hexyl CELLOSOLVE solvent. Glycol Ether DB Safety Data Sheet according to Federal Register / Vol. Hexyl CELLOSOLVE Solvent (Ethylene Glycol Monohexyl Ether). It is a diluent for hydraulic brake fluids and an intermediate in the manufacture of plasticizers. For several of the products, special Health Effects Overviews and Toxicology Summaries have been prepared. Butyl rubber or EPDM can be used for gaskets and packing. Dow has carried out a series of laboratory studies on the biodegradation and ecological effects of its glycol ethers. Properties of Glycol Ethers Glycol Ethers Background. It is also a coalescing aid for polyvinyl acetate latexes. DOW Glycol Ether products, as well as the materials to manufacture them, are produced to exacting standards. Components of paper and paperboard in contact with dry food only. Shipping Data It attacks some forms of plastics, rubber and coatings. Ethereal. Methyl CARBITOL solvent offers both excellent solvency and low volatility. Methoxytriglycol (Triethylene Glycol Monomethyl Ether), Ethoxytriglycol (Triethylene Glycol Monoethyl Ether), Butoxytriglycol (Triethylene Glycol Monobutyl Ether). No specific requirements for continued use, but EPA may issue data call-ins for toxicology data. For example, Butyl CELLOSOLVE solvent becomes less soluble and separates from solution as the solution temperature is increased (See Figure 6). Measured value determined by chemical oxygen demand procedure published in Standard Methods for the Examination of Water and Wastewater, 18th ed, Am Public Health Assoc., Washington, DC (1992). The product line consists of more than 10 distinct chemicals. Consult the U.S. Department of Transportation Shipping Manual. Additionally, an appropriate desiccant system may be chosen to prevent moisture pickup during storage or turnover of the tank contents. In use since the 1930s, glycol ethers are solvents that dissolve both water-soluble and hydrophobic substances. Ethylene glycol ethers and glycol ether acetates are clear liquids with mild, pleasant odors. Related applications include special coatings for polystyrene, epoxy coatings and high-low thinners for viscosity reduction of alkyd baking enamels. FDA Status Glycol Ether EB has excellent solvency for a variety of resins including acrylic, alkyd, phenolic, epoxy, nitrocellulose and urethane resins. Glycol Ether (EB) can solvate both water-soluble and hydrophobic materials. Solvent in the formulation of polysulfide polymer-polyepoxy resins used as the food-contact surface for dry food.    – Vapor Pressure Curves Information On Glycol Ether From Wikipedia Glycol ethers are a group of solvents based on alkyl ethers of ethylene glycol or propylene glycol commonly used in paints and cleaners. Propyl CELLOSOLVE solvent is useful in printing and other specialized coatings applications. For Material Safety Data Sheets and other product safety information, contact. Glycol ethers are selected for specific purposes, suc… Most importantly, Dow is the world’s leading producer of many of the principal raw materials used to manufacture glycol ethers: ethanol, n-propanol, n-butanol and ethylene oxide. Butyl CELLOSOLVE Solvent (Ethylene Glycol Monobutyl Ether). They are extensively used as solvents in industrial processes and manufacturing and as thinner and viscosity improving agents in coating processes. removers, metal cleaners and rust removers. In fact, glycol ether EB is the prime ingredient in hundreds of cleaning solutions used worldwide because of its ability to break down both hydrophilic and hydrophobic particles. Vapor Pressures for Selected Propyl, Butyl & Hexyl Glycol Ethers. Butyl CARBITOL Solvent (Diethylene Glycol Monobutyl Ether). Methyl CARBITOL solvent is suitable for dyes, oils, fats, waxes and resins. Considering 200-500 kilotons of glycol ether are produced annually, chances are your business depends on this United States high-production volume chemical (a chemical whose production exceeds 100 kilotons a year) to keep it running smoothly. The Dow Chemical Company is the world’s leading producer of ethylene-oxide-based glycol ethers, both in product-line breadth and total volume produced. Bacterial growth inhibition tests(3) indicate that none of the DOW Glycol Ether products should be inhibitory to conventional biological wastewater treatment processes at reasonable discharge levels [500 to 1000 mg/L in compliance with applicable regulations], and they would be expected to undergo rapid biodegradation in the concentrated biomass of these systems. Health Hazards: Irritating to Eyes Safety Hazard: Not classified as FLAMMABLE, but will burn HEALTH HAZARD: Skin Contact: May cause moderate irritation to skin. Hexyl CELLOSOLVE solvent plays an important role in specialty printing inks. Most tested glycol ethers show LC50 / EC50 values above 1000 mg/L. Thousands of industries rely on glycol ether EB. Some brand names for glycol ethers include Cellosolve, R Carbitol, R Dowanol, R and Ektasolve. IZ180(N)LIQUID-1184 . LyondellBasell offers a broad line of glycol ethers based on ethylene and propylene. (2) Determined by turbidity/growth procedures where the median inhibition concentration (IC50) is measured after 16 hours of incubation with sewage microorganisms. DOW Glycol Ether products are produced through continuous processes of selectively reacting an alcohol and ethylene oxide. Typically, e-series glycol ethers are found in pharmaceuticals, sunscreens, cosmetics, inks, dyes and water-based paints, while p-series glycol ethers are used in degreasers, cleaners, aerosol paints and adhesives. If there are no residues that can be considered as additives under these conditions, FDA regulations are not applicable. No chemical should be used as or in a food, drug, medical device, or cosmetic, or in a product or process in which it may contact a food, drug, medical device or cosmetic until the user has determined the suitability and legality of the use. The ether groups introduce additional sites for hydrogen bonding with improved hydrophilic solubility performance. These tests were conducted by procedures that follow EPA(4,5,6)/ASTM(7)/ OECD(8) techniques. In fabric cleaners, Butyl CELLOSOLVE solvent assists in removing water-soluble stains and aids in brightening the colors of garments. H336 May cause drowsiness or dizziness. Hexyl CARBITOL Solvent (Diethylene Glycol Monohexyl Ether). Solvent in certain sanitizing solutions for food-processing equipment and utensils. These solvents typically have a higher boiling point, together with the favorable solvent properties of lower-molecular weight ethers and alcohols. The alkoxytriglycols are also useful as components of high boiling hydraulic brake fluids. At temperatures above 50°C, it may be possible to decant an aqueous layer from an upper organic layer, thus reducing the organic content of the aqueous waste stream. … In long-term storage, nitrogen-blanketing of tanks may be desired to pre-empt any tendency of the glycol ethers to oxidize, which shows itself as an increase in acidity. Ethoxytriglycol is a possible exception, since it freezes at -9°F (-23°C). Glycol ethers, as a class of chemicals having longer hydrocarbon-like alkoxide groups, display solubility more characteristic of hydrocarbons. In some cases, this process can be utilized to remove Butyl CELLOSOLVE solvent from an aqueous waste stream. Glycol ethers have several applications in industry as lubricants, colorants, and plasticizers. HAZARDS IDENTIFICATION Emergency Overview Appearance: liquid, colourless WARNING! Butyl CELLOSOLVE solvent is an excellent solvent widely used in coatings and cleaner applications, including many directed to consumer markets. This varies based on the type of coating or paint. The alkoxytriglycols are useful as low-volatility components in paint stripping formulations, as dye carriers for textile dye processes, as chemical process solvents and as intermediates for making esters for use as solvents, surfactants and plasticizers. Butyl CELLOSOLVE solvent offers superior performance in many hard-surface cleaners and related cleaning formulations. (5) EPA, CFR 797.1400, Fish Acute Toxicity Test, February 1997. Mineral oils, water and soaps are miscible with Butyl CELLOSOLVE solvent. Inert (or occasionally active) ingredients for use in formulations applied to growing crops only up to time of harvest. † The physical property data listed are considered to be typical properties, not specifications. Several glycol ethers have been cleared by the Environmental Protection Agency (EPA) for use as inert ingredients in pesticide formulations under EPA Regulation 40 CFR 180.1001. Small quantities of CARBITOL solvent in these mixtures form translucent-to-clear dispersions, in contrast to the usual turbid dispersion that indicates incomplete solubility. Component of defoaming agents used in the manufacture of paper and paperboard. Selected DOW Glycol Ether Products. These characteristics, as well as its high boiling point and low vapor pressure, make it useful for twist setting and yarn and cloth conditioning. Product Profiles As a class of products, CELLOSOLVE and CARBITOL solvents are: This strong solvency leads to the selection of certain CELLOSOLVE and CARBITOL solvents and the alkoxytriglycol glycol ethers for a broad array of end-uses: Members of the CELLOSOLVE and CARBITOL solvent families are also useful chemical intermediates. Due to the presence of both an ether and a hydroxyl group in the same molecule, these products are miscible in water, as well as most organic solvents. Heated storage is not normally required. They have relatively low vapor pressures. (2) Included in EPA list of Potentially Toxic Inerts/High Priority for Testing (ibid.). Butyl CARBITOL solvent serves as a mutual solvent for soaps, oils and water and as a component of liquid cleaners, “soluble” oils and textile oils. Aquatic toxicity measurements show effects ranging from slightly toxic to relatively nontoxic with tested species, which included fathead minnows and Daphnia Magna. Butyl CARBITOL solvent is used as a solvent in formulating aids for latex paints and as a dispersant for vinyl chloride resins used in organosols. OECD 301-B Carbon Dioxide Evolution Biodegradation Testing(1). Liquid. Glycol Ether EB Acetate 29 November 2017 _____ SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures: Technical measures and appropriate working operations should be given priority over the use of personal protective 8.2 Exposure controls 8.1 Control parameters Advice on protection against fire and explosion Avoid sources of ignition. (1) Pensky-Martens Closed Cup unless otherwise noted. Glycol Ether DB (Diethylene Glycol Monobutyl Ether) is a colorless liquid that is miscible with water and most organic solvents. Diethylene Glycol Butyl Ether Product Page. If there are no residues that … (3) EPA/ASTM bioassay procedures were followed in obtaining these values. Your business can undoubtedly use it as a safe, effective dispersant and solvent as well. These solvents are widely used paints & coatings, industrial cleaners, and inks. DOW Glycol Ether products do not present a significant flammability hazard. Soluble in tetrachloromethane. Since government regulations and use conditions are subject to change, it is the user’s responsibility to determine that this information is appropriate and suitable under current, applicable laws and regulations. Mild-odored solvents for many resins, oils, waxes, fats and dyestuffs, Coupling agents for many water/organic systems, Miscible with a wide range of polar and non-polar organic solvents, Dye solvents in the textile, leather and printing industries, Solvents for grease and grime in industrial cleaning and specialty formulations, Solvents for insecticides and herbicides for agricultural applications, Coupling solvents for hard-surface cleaners and other soap-hydrocarbon systems, Solvents and cosolvents for conventional lacquer, enamel and stains for industrial coating systems, Cosolvents for waterborne industrial coating systems, Reaction with carboxylic acids, carboxylic acid chlorides, anhydrides and inorganic acids to produce esters, Reaction with organic halides to produce ethers, such as glymes, Reaction with alkenes and alkynes to produce ethers, Reaction with halogenating agents to produce alkoxy alkyl halides, Reaction with epoxides to produce polyether alcohols, Reaction with aldehydes and ketones to produce hemiacetals and acetals. LT313-4440 . † The physical property data listed are considered to be typical properties, not specifications. Technical Service. Glycol ethers, with both an ether and alcohol functional group in the same molecule, are one of the most versatile classes of organic solvents. (1) Calculated theoretical oxygen demand (THOD) based on complete oxidation of the chemical to carbon dioxide and water. Glycol Ether EB Version 1.11 Revision Date: 09/05/2019 SDS Number: 100000002203 2 / 12 Glycol Ether EB H319 Causes serious eye irritation. 58 / Monday, March 26, 2012 / Rules and Regulations 05/01/2018 EN (English US) 2/8 P271 - Use only outdoors or in a well-ventilated area P280 - Wear eye protection, face protection, protective clothing, protective gloves Glycol Ethers are a family of chemicals with key solvent properties used in various and diverse applications. Temperature. Vapor Pressures for Selected Methyl and Ethyl Glycol Ethers, Figure 5. Mineral oil-soap and mineral oil-sulfonated oil mixtures require fast-acting mutual solvents. Reproduction of any materials from the site is strictly forbidden without permission. | Privacy. The petroleum industry relies on glycol ether EB as a drilling stabilizer, oil slick dispersant, and in water-based and oil-based fracturing fluids. Ten test organisms were used per test concentrations. Registration dossier . Glycol ether’s unique chemical structure of an alcohol and an ether give it hydrophobic and water soluble properties. Glycol ethers are a group of solvents based on alkyl ethers of ethylene glycol or propylene glycol commonly used in paints and cleaners. (6) EPA, CFR 797.1300, Daphnid Acute Toxicity Test, February 1997. Both E-series glycol ethers and P-series glycol ethers can be used … DOW Glycol Ether products can be stored and piped in carbon steel. Eastman™ EB Acetate (Ethylene Glycol Monobutyl Ether Acetate) is a high boiling glycol ether-ester. What’s actually in the chemical, though? NOTE: Dow does not recommend using aluminum, copper, galvanized iron, galvanized steel, Viton elastomers, neoprene or natural rubber with its glycol ethers. © 2021  Merck KGaA, Darmstadt, Germany and/or its affiliates. Manufacturers of these chemicals are members of the Oxygen Solvents Producers Association (OSPA), a branch of the European Solvents Industry … It is widely used as a solvent, especially in the printing ink and paint industries. Certain glycol ethers are presently cleared under regulations of the United States Food and Drug Administration (FDA) for use in food-related applications. Soluble in heptane. Glycol Ether EB is a clear liquid with mild, pleasant odors. Distributor Availability A fast-evaporating, hydrophobic glycol ether with high solvency and excellent coupling abilities. It is liable to form peroxides on exposure to air and light. It can be used with associative thickeners to enhance application properties such as brushability or roll application in high performance coatings. No smoking. It is a slow evaporating solvent that partitions primarily into the polymer phase of a waterborne coating and reduces Minimum Filming Temperature. Sigma-Aldrich Products are sold exclusively through Sigma-Aldrich, Inc. Glycol ether lowers the surface tension of products, stabilizing fluids pumped under extremely high pressures. Glycol ethers consist of two components, an alcohol and ether. (2) The material meets the criteria if it passes from 10% biodegradable to 60% biodegradable within a 10-day period. Glycol ethers are quite stable when proper handling and storage conditions are employed. Eastman™ EB Solvent is also widely used in amine-solubilized, water-based coatings … All of the DOW Glycol Ether products with the exception of butoxyglycol would be classified as “readily”/rapidly biodegradable and would not be expected to persist in the natural environment for a significant period of time. (2) OECD Guidelines for Testing of Chemicals, Organization for Economic Cooperation and Development, Vol. The linear hexyl portion of Hexyl CELLOSOLVE solvent provides excellent oil solubility characteristics that make it useful in both consumer and industrial cleaner applications. It improves penetrating and wetting action of phosphoric acid-type rust removers. For quantities of 55 Gallons, we will contact you with a shipping quote prior to processing your order. MAY BE HARMFUL IF … Site Use Terms Surface Tension of Aqueous Solutions for Selected CARBITOL Solvents, Figure 3. The USFDA has deemed glycol ether appropriate for use directly and indirectly within the food industry as an ingredient in adhesives, antimicrobial agents, defoamers, and stabilizers. GLYCOL ETHER DB 1. Heating the aqueous EB extract solution to 55 °C formed two liquid phases: a glycol ether‐rich phase and an aqueous product phase containing the great majority of the product protein. Mutual Solubility of Butyl CELLOSOLVE Solvent/Water vs. Customers of the industrial chemical supplier, Bell Chem, have found glycol ether EB useful as a surfactant in the home, in businesses, and industrially. Surface Tension of Aqueous Solutions for Selected Alkoxytriglycols, Figure 4. This feature can be used to enhance the solvent effect of Butyl CELLOSOLVE solvent in aqueous solutions. Registration dossier . Glycol ethers are characterized by their excellent solvency, chemical stability and compatibility with water and a number of organic solvents. ETHYLENE GLYCOL N-BUTYL ETHER may react with bases, aluminum and oxidizing materials. Butyl CARBITOL solvent is a dye solvent used to promote rapid and uniform ink penetration for printing box-board and similar materials. Product Safety It is an exceptional retarder solvent for lacquers, improving gloss and flow-out. (7) Annual Book of ASTM Standards, Water and Environmental Technology, Vol.11.05, (1995). Surface Tension of Aqueous Solutions for Selected CELLOSOLVE Solvents, Figure 2. It is used in household cleaners, liquid soaps, cosmetics spray lacquers, enamels, herbicides, hydraulic fluids, fabric dyes and inks, household degreasers, dry-cleaning substances, and latex paints. The product’s mild odor and ability to improve dye penetration make it attractive for non-grain-raising wood stains, spirit-type dyes and textile dye pastes. Biodegradation testing was conducted following methods published by the Environmental Protection Agency (EPA)(1) and Organization for Economic Cooperation and Development (OECD)(2). MAY AFFECT THE CENTRAL NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. Properties of Selected Glycol Ethers†. Chemistry Mission Models Thinner . Soluble in oil. Soluble in ethanol. 2, Section 3, Degradation and Accumulation, Updated 1993. 58 / Monday, March 26, 2012 / Rules and Regulations 02/13/2018 EN (English US) 5/8 Solubility : Soluble in water. Als Lösungsmittel haben Glycolether typischerweise die vorteilhaften Lösungsmitteleigenschaften von Ethern und Alkoholen niedrigerer Molekülmassen, jedoch höhere Siedepunkte, was für die Verarbeitung vorteilhaft ist. Methyl CARBITOL Solvent-Fuel System Icing Inhibitor (FSII) is used by the aviation industry according to U. S. Military Specification MIL-I-85470 and equivalents around the world to prevent icing in aircraft jet fuel systems. EPA Status Glycol ether EB . Formulating with Glycol Ethers Article The recommended resample times for glycol ethers are 24 months for drums, 12 months for bulk and 6 months for samples. Many cleaners and protectants contain glycol ether as an ingredient, including leather buffers, whiteboard cleaners, liquid hand and body soap, and dry cleaning solutions. Glycol Ether EB Safety Data Sheet according to Federal Register / Vol. Registration dossier . Starting At: $ 15.00. Significant differences exist in product toxicity and corresponding exposure levels considered appropriate for different products within the family. 77, No. Applications Properties of Selected Glycol Ethers†. Our blogs contain information on chemicals and food additives, including nutritional supplements, personal care ingredients, sanitation chemicals, and technical-grade chemicals. Glycol Ether EB is affordably priced solvent that can dissolve both hydrophobic and water soluble compounds, and is a solvent for paints, inks, cleaning products. Glycol ethers have relatively low viscosities and freezing points. (4) Methods for Measuring the Acute Toxicity of Effluents to Freshwater and Marine Organisms, EPA/600/4-85/O1 3, March 1985 These substances are … In addition, Butyl CELLOSOLVE solvent is the most widely used cosolvent for industrial waterborne coatings due to its excellent balance of volatility, resin solvency and oil/water solubility. It has limited water miscibility. (3) Decomposes at 760 mmHg, boiling point extrapolated. Glycol ethers have many uses; these include use as solvents and as an ingredient in cleaning compounds, liquid soaps, and cosmetics. IDENTIFICATION MSDS Name: Diethylene Glycol Monobutyl Ether Synonyms: Butyl Carbitol, Glycol Ether DB, Butyl Di Glycol 2. How to tell if a product has 2-Butoxyethanol Glycol ether lowers the surface tension of products, stabilizing fluids pumped under extremely high pressures. (1) This test method monitors carbon dioxide produced from the biooxidation of molecular carbon in the test substance. IZ180(N)LIQUID-1184(H) Registration dossier . Hexyl CELLOSOLVE solvent is a high boiling point, slow evaporating solvent with excellent solvency characteristics. It strengthens blush resistance and is one of the best retarders for nitrocellulose lacquers. (2) Percent by weight; 90% Hexyl CELLOSOLVE solvent: 10% water (solubility limitations). With over 300 types of glycol ethers, customers are able to select the appropriate chemical with the flame resistance, solubility, and volatility they require. Hexyl CARBITOL solvent has shown excellent performance in cleaning formulation for the removal of greasy soils. Eastman EB Solvent (Ethylene Glycol Monobutyl Ether) offers numerous benefits in coating, ink, and cleaner applications. As a solvent, glycol ether is an ingredient in many coatings, including latex paints, resins, lacquers, varnishes, and enamels. Precautionary statements : Prevention : P210 Keep away from heat/sparks/open flames/hot surfaces. When considering the use of any Dow products in a particular application, you should review Dow’s latest Material Safety Data Sheets and ensure that the use you intend can be accomplished safely.